Dioxins (polychlorinated dibenzodioxins, PCDDs) are among the most hazardous substances produced during waste incineration. Their emissions are regulated by law and must be monitored at all times. Current continuous sampling methods are time-consuming and provide only average values on dioxin leakage, depending on the time of integration. Real-time on-line measurements to determine dioxin concentration and the parameters of its formation are rare.